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Rh2sub>O3sub>/hexagonal CePO4sub> nanocatalysts for N2sub>O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4, Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

Keywords： Rh2sub>O3sub> CePO4sub> N2sub>O decomposition

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The stabilization effect of Al2sub>O3sub> on unconventional Pb/SiO2sub> catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10, Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al2sub>O3sub> with a small amount, wasintroduced into Pb/SiO2sub> catalyst in this study.It has been proved that Al2sub>O3sub> can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO2sub> catalyst exhibits a much higher stability up to more than 150 h.>2sub>O3sub> addition was also proposed.

Keywords： Pb/SiO2sub> Al2sub>O3sub> propane dehydrogenation propene stability

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Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr2sub>O3sub> Systemwith Al2sub>O3sub> and Cr2sub>O3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Strategic Study of CAE 2004, Volume 6, Issue 6, Pages 63-67

Abstract:

The thermodynamic calculation and analysis of combustion synthesis reaction of Al - Cr2O3 system with AI2O3and Cr2O3 diluents were conducted, and the effects of reactionstarting temperature TO, diluents AI2O3 and Cr2O3 on the adiabatic combustion temperature

Keywords： cermet combustion synthesis Al - Cr2sub>O3sub> system thermodynamics reaction model

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CO2sub> methanation and co-methanation of CO and CO2sub> over Mn-promoted Ni/Al2sub>O3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 2, Pages 273-280 doi: 10.1007/s11705-016-1563-5

Abstract: A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnation method. The effect of the Mn content on the activity of the Ni/Al O catalysts for CO methanation and the co-methanation of CO and CO in a fixed-bed reactor was investigated. The catalysts were characterized by N physisorption, hydrogen temperature-programmed reduction and desorption, carbon dioxide temperature-programmed desorption, X-ray diffraction and high-resolution transmission electron microscopy. The presence of Mn increased the number of CO adsorption sites and inhibited Ni particle agglomeration due to improved Ni dispersion and weakened interactions between the nickel species and the support. The Mn-promoted 15 wt-% Ni/Al O catalysts had improved CO methanation activity especially at low temperatures (250 to 400 °C). The Mn content was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-Ni/Al O catalyst. The co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the CO methanation activity especially at low temperatures but it had little influence on the CO methanation performance. CO methanation was more sensitive to the reaction temperature and the space velocity than the CO methanation in the co-methanation process.

Keywords： Mn promotion nickel catalysts CO2sub> methanation co-methanation of CO and CO2sub>

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Al2sub>O3sub> and CeO2sub>-promoted MgO sorbents for CO2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1, Pages 83-93 doi: 10.1007/s11705-017-1691-6

Abstract: A series of Al O and CeO modified MgO sorbents was prepared and studied for CO sorption at moderate temperatures. The CO sorption capacity of MgO was enhanced with the addition of either Al O or CeO . Over Al O -MgO sorbents, the best capacity of 24.6 mg-CO /g-sorbent was attained at 100 °C, which was 61% higher than that of MgO (15.3 mg-CO /g-sorbent). The highest capacity of 35.3 mg-CO /g-sorbent was obtained over the CeO -MgO sorbents at the optimal temperature of 200 °C. Combining with the characterization results, we conclude that the promotion effect on CO sorption with the addition of Al O and CeO can be attributed to the increased surface area with reduced MgO crystallite size. Moreover, the addition of CeO increased the basicity of MgO phase, resulting in more increase in the CO capacity than Al O promoter. Both the Al O -MgO and CeO -MgO sorbents exhibited better cyclic stability than MgO over the course of fifteen CO sorption-desorption cycles. Compared to Al O , CeO is more effective for promoting the CO capacity of MgO. To enhance the CO capacity of MgO sorbent, increasing the basicity is more effective than the increase in the surface area.

Keywords： CO2sub> capture MgO sorbents Al2sub>O3sub> CeO2sub> flue gas

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In-MOF-derived In2sub>S3sub>/Bi2sub>S3sub> heterojunction for enhanced photocatalytic

Frontiers in Energy 2023, Volume 17, Issue 5, Pages 654-663 doi: 10.1007/s11708-023-0885-5

Abstract: In this paper, a broad spectrum responsive In2sub>S3sub>/Bi2sub>S3sub> heterojunctionis constructed by in-situ integrating Bi2sub>S3sub> with the In2sub>S2sub>S3sub>/Bi2sub>S3sub> heterojunction demonstrates a rate of 0.71 mmol/(g∙h), which is 2.2 and 1.7 times as much as those of In2sub>S3sub> (0.32 mmol/(g∙h) and Bi2sub>S3sub> (0.41 mmol/(g∙h)), respectively.

Keywords： photocatalytic hydrogen production wide-spectrum response metal sulfides MOFs derivative heterogeneous interfacial contact

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Feasibility study of plasma sprayed Al2sub>O3sub> coatings as diffusion barrier on CFC

Kirsten BOBZIN, Lidong ZHAO, Nils KOPP, Thomas WARDA

Frontiers of Mechanical Engineering 2012, Volume 7, Issue 4, Pages 371-375 doi: 10.1007/s11465-012-0339-y

Abstract: Within this study the feasibility of plasma sprayed Al2sub>O3sub> coatings as diffusionAl2sub>O3sub> coatings were prepared by air plasma spraying (APS).The results showed that Al2sub>O3sub> could be well deposited onto CFC substrates.temperature of 1270°C, crack network formed within the coating, showing that the plasma sprayed Al2sub>O3sub> coatings are limited regarding to their application temperatures as diffusion

Keywords： diffusion barrier coatings CFC plasma spraying microstructure Al2sub>O3sub>

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Spray Preparation, Microstructure and Properties of Al2sub>O3sub>-Mxsub>O Hard -

Wang Biao,Wang Yudong,Li Huiling,Zhang Zihua

Strategic Study of CAE 2002, Volume 4, Issue 9, Pages 75-80

Abstract: carbon steel substrate, base coating of nickel-coated aluminium and intermediate coating of 50% Al2sub>O3sub> + 50% Ni were prepared by means of oxyacetylene spray, and final coating of Al2sub>O3sub> ～ Mxsub>Oysub> was prepared by means of plasma spray.of 60% (mass) sulphuric acid with 60 % concentration, and 40% (mass) phosphoric ore powder, the Al2sub>O3sub> ～ Mxsub>Oysub> coating resistance to corrosion and wear, is 7.46

Keywords： Al2sub>O3sub>-Mxsub>Oysub> coating plasma resistance to corrosion resistance

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Evaluation of H2sub> on the Evolution Mechanism of NOxsub> Storage and Reductionover Pt–Ba–Ce/γ-Al2sub>O3sub> Catalysts Article

Pan Wang, Jing Yi, Chuan Sun, Peng Luo, Lili Lei

Engineering 2019, Volume 5, Issue 3, Pages 568-575 doi: 10.1016/j.eng.2019.02.005

Abstract:

In this investigation, Pt–Ba–Ce/γ-Al2sub>O3sub> catalysts were preparedThe physical and chemical properties of the Pt–Ba–Ce/γ-Al2sub>O3sub>>xsub>, CeO2sub>, and BaCO3sub>, whose peaks were observed in X-ray diffraction(XRD) spectra, dispersed well on the γ-Al2O3, as shown by transmission electron microscope (TEM>catsub> at 350 °C, which was ascribed to the increase in NO2sub> yield.

Keywords： Pt–Ba–Ce/γ-Al2sub>O3sub> catalysts Physicochemical properties NOxsub> storageand reduction NOxsub> emission H2sub> reductant

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Highly selective catalytic hydrodeoxygenation of guaiacol to cyclohexane over Pt/TiO

Zhong HE,Xianqin WANG

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 3, Pages 369-377 doi: 10.1007/s11705-014-1435-9

Abstract: Catalysts Pt/TiO and NiMo/Al O are highly active and selective for the hydrodeoxygenation of guaiacol in a fixed bed reactor at 300 °C and 7.1 MPa, leading to the hydrogenation of aromatic ring, followed by demethylation and dehydroxylation to produce cyclohexane. For a complete hydrodeoxygenation of guaiacol, metal sites and acid sites are required. NiMo/Al O and Pt/Al O are more active and selective for cyclohexane formation as compared with Pt/TiO at 285 °C and 4 MPa. However, Pt/TiO is stable while the other two catalysts deactivate due to the nature and amount of coke formation during the reaction.

Keywords： Pt/TiO2sub> NiMo/Al2sub>O3sub> Pt/Al2sub>O3sub> bio-oil hydrodeoxygenation

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Comparison study on strategies to prepare nanocrystalline Li

Qiang XIAO, Xiaodan TANG, Yefeng LIU, Yijun ZHONG, Weidong ZHU

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 3, Pages 297-302 doi: 10.1007/s11705-013-1346-1

Abstract: A comparison study has been conducted on the strategies for synthesizing nanocrystalline Li ZrO and K-doped Li ZrO absorbents for CO capture at high temperatures, including solid-state and liquid-phase methods, citrate route, and starch-assisted sol-gel method combined with freeze-drying technique. The absorption properties, including uptake rate and absorption capacity, of synthesized absorbents were investigated by thermogravimetric analysis (TGA) at different CO partial pressures. The nanosized Li ZrO crystals synthesized by the citrate route exhibit a faster uptake and a higher, nearly stoichiometric absorption capacity than those synthesized by the solid-state and liquid-phase methods. The doping of K into Li ZrO can significantly improve the uptake rate of CO , especially at low CO partial pressures. For the synthesis of K-doped Li ZrO , the citrate route has poor reproducibility and scalability, whereas the starch-assisted sol-gel method combined with freeze-drying technique is reproducible and easily scaled up, and the thus synthesized absorbents possess excellent CO capture properties.

Keywords： CO2sub> capture Li2sub>ZrO3sub> K-doped Li2sub>ZrO3sub> citrate starch

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Piezocatalytic performance of FeO−BiMoO catalyst for dye degradation

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 6, Pages 716-725 doi: 10.1007/s11705-022-2265-9

Abstract: A Fe2sub>O3sub>−Bi2sub>MoO6sub> heterojunction was synthesized via a hydrothermalThe highest rhodamine B degradation rate of 96.6% was attained on the 3% Fe2sub>O3sub>−>2sub>O3sub> and Bi2sub>MoO6sub>, which effectively separated the ultrasound-induced>3sub>−Bi2sub>MoO6sub> catalyst was proposed based on the band potential and quenchingThe results demonstrated the potential of using Fe2sub>O3sub>−Bi2sub>MoO6

Keywords： piezocatalysis Fe2sub>O3sub>−Bi2sub>MoO6sub> dye decomposition ultrasonic

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Removal of P4sub>, PH3sub> and H2sub>S from Yellow Phosphoric Tail Gas by a Catalytic

Ning Ping,Hans-Jörg Bart,Wang Xueqian,Ma Liping,Chen Liang

Strategic Study of CAE 2005, Volume 7, Issue 6, Pages 27-35

Abstract: sulfide in yellow phosphorus tail gas was investigated with activated carbon and a home-made catalyst KU2.Both KU2 and activated carbon proved to be effective catalysts in the catalytic oxidation process (COP) for H2sub>S and PH3sub> removal.Under optimized operation conditions the product gas with a content of hydrogen sulfide ＜5 mg/m³, total phosphorus＜ 5 mg/m³ was obtained by using the COP process.

Keywords： catalyst catalytic oxidation H2sub>S P4sub> PH3sub> fixed bed

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Interfacial charge transfer and photocatalytic activity in a reverse designed BiO/TiO core-shell

Frontiers in Energy 2021, Volume 15, Issue 3, Pages 732-743 doi: 10.1007/s11708-021-0772-x

Abstract: photocatalytic properties of core-shell heterojunctions photocatalysts with reversible configuration of TiO2sub> and Bi2sub>O3sub> layers were studied.The results show the formation of homogenous TiO2sub> anatase and Bi2sub>O3sub>In optimal core-shell design, Bi2sub>O3sub> collects holes from TiO2sub>, leavingelectrons free to react and increase by 5 times the photocatalytic efficiency toward H2sub> generation

Keywords： photocatalysis core-shell heterojunction H2sub> TiO2sub> Bi2sub>O3sub

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acid anions on highly efficient Ce-based catalysts for selective catalytic reduction of NO with NH3sub>

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10, Pages 1399-1411 doi: 10.1007/s11705-023-2345-5

Abstract: 3sub>) were synthesized and used for the selective catalytic reduction (SCR) of NO by NH3> Ce2sub>(SO4sub>)3sub>, which is in agreement with their abilities of NH3sub>4sub>^3–, VO4sub>^3– and SO4sub>^{2–sub>3sub> temperature programmed desorption, H2sub>>2sub> for Ce2sub>(SO4sub>)3sub>.}

Keywords： CePO4sub> CeVO4sub> Ce2sub>(SO4sub>)3sub> selective catalytic reduction

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Title Author Date Type Operation

Rh2sub>O3sub>/hexagonal CePO4sub> nanocatalysts for N2sub>O decomposition

Huan Liu, Zhen Ma

Journal Article

The stabilization effect of Al2sub>O3sub> on unconventional Pb/SiO2sub> catalyst

Journal Article

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr2sub>O3sub> Systemwith Al2sub>O3sub> and Cr2sub>O3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Journal Article

CO2sub> methanation and co-methanation of CO and CO2sub> over Mn-promoted Ni/Al2sub>O3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Journal Article

Al2sub>O3sub> and CeO2sub>-promoted MgO sorbents for CO2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Journal Article

In-MOF-derived In2sub>S3sub>/Bi2sub>S3sub> heterojunction for enhanced photocatalytic

Journal Article

Feasibility study of plasma sprayed Al2sub>O3sub> coatings as diffusion barrier on CFC

Kirsten BOBZIN, Lidong ZHAO, Nils KOPP, Thomas WARDA

Journal Article

Spray Preparation, Microstructure and Properties of Al2sub>O3sub>-Mxsub>O Hard -

Wang Biao,Wang Yudong,Li Huiling,Zhang Zihua

Journal Article

Evaluation of H2sub> on the Evolution Mechanism of NOxsub> Storage and Reductionover Pt–Ba–Ce/γ-Al2sub>O3sub> Catalysts

Pan Wang, Jing Yi, Chuan Sun, Peng Luo, Lili Lei

Journal Article

Highly selective catalytic hydrodeoxygenation of guaiacol to cyclohexane over Pt/TiO

Zhong HE,Xianqin WANG

Journal Article

Comparison study on strategies to prepare nanocrystalline Li

Qiang XIAO, Xiaodan TANG, Yefeng LIU, Yijun ZHONG, Weidong ZHU

Journal Article

Piezocatalytic performance of FeO−BiMoO catalyst for dye degradation

Journal Article

Removal of P4sub>, PH3sub> and H2sub>S from Yellow Phosphoric Tail Gas by a Catalytic

Ning Ping,Hans-Jörg Bart,Wang Xueqian,Ma Liping,Chen Liang

Journal Article

Interfacial charge transfer and photocatalytic activity in a reverse designed BiO/TiO core-shell

Journal Article

acid anions on highly efficient Ce-based catalysts for selective catalytic reduction of NO with NH3sub>

Journal Article

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